You can modify the sector size of NVMe devices by removing the device from VxVM and reformatting it.
To reformat NVMe devices manually
# vxdisk offline r720xd-114217_intel_nvme0_0
# vxdisk rm r720xd-114217_intel_nvme0_0
# echo 1 > /sys/block/nvme0n1/device/device/remove
# vxdisk scandisks
# vxdisk list | grep nvme
# echo 1 > /sys/bus/pci/rescan # echo 1 > /sys/bus/pci/drivers/nvme/0000\:05\:00.0/rescan
# isdct start -intelssd 0 -nvmeformat LBAFormat=3 SecureEraseSetting=0 \ ProtectionInformation=0 MetadataSettings=0 WARNING! You have selected to format the drive! Proceed with the format? (Y|N): y Formatting... - Intel SSD DC P3700 Series CVFT5456000V2P0EGN - Status : NVMeFormat successful.
# vxdisk scandisks
# vxdisk list | grep nvme r720xd-114217_intel_nvme0_0 auto:none - - online invalid